Why are my debit card transactions still pending?

Deposited my check Saturday night for $219. The bank was open on Sunday from 1:30-4:00. Anyway, made an online purchase on Sunday for $101, later on bought a wallet for $21, bought dinner for $17, bought my boyfriend cigarettes for $6,all of that on sunday, and then he used my card yesterday for $6. I called to get my balance, it said ledger balance of $192, and available balance of $66. Went to check the pending transactions and they were the online purchase, the dinner, and the $6 from yesterday. Why arent they clearing? And why did the other ones clear and not these? I need them to hurry up so my onliine order can process and ship. Anyone have any info as to why this is?